THE OXIDATION OF ETHANE-1,2-DIOL RESULTING FROM MOLECULAR-OXYGEN ACTIVATION BY COPPER - FORMATION OF AN OXOETHANOATE COMPLEX PRECEDES CARBON-CARBON BOND-CLEAVAGE

被引：22

作者：

LANFRANCHI, M

PRATI, L

ROSSI, M

TIRIPICCHIO, A

机构：

[1] UNIV MILAN,DIPARTIMENTO CHIM INORGAN MET ORGAN & ANALIT,CTR CNR,VIA VENEZIAN 21,I-20133 MILAN,ITALY

[2] UNIV PARMA,IST CHIM GEN & INORGAN,CNR,CTR STUDIO STRUTTURIST DIFFRATTOMETR,I-43100 PARMA,ITALY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 22期

关键词：

D O I：

10.1039/c39930001698

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The aerial oxidation of ethane-1,2-diol in the presence of copper metal and pyridine (py) at room temperature and atmospheric pressure produces [Cu(py)2(HCO2)2].H2O and [Cu2(py)4(OCH2CO2)2].(CH2OH)2; the structure of the latter has been fully elucidated by an X-ray study.

引用

页码：1698 / 1699

页数：2

共 8 条

[1] SQUARE-PYRAMIDAL COPPER COMPLEX CONTAINING BOTH MONODENTATE AND ANTI-SYN BRIDGING FORMATE GROUPS - CRYSTAL-STRUCTURE OF CATENA-MU-FORMATO-FORMATOBIS(PYRIDINE)COPPER(II) MONOHYDRATE [J].