1 - 1 ADDUCTS OF SQUARE-PLANAR NICKEL CHELATES WITH AMINES

被引：41

作者：

SGAMELLOTTI, A

FURLANI, C

MAGRINI, F

机构：

[1] Institute of General and Inorganic Chemistry, the University of Perugia

来源：

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY | 1968年 / 30卷 / 10期

关键词：

D O I：

10.1016/0022-1902(68)80392-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Bis (diethyldithiophosphat) nickel (II), bis (diphenyldithiophosphinat) nickel (II) and other square planar sulphur-containing nickel chelates yield paramagnetic 1:1 adducts with several nitrogen bases; with primary aliphatic amines, formation of the 1:1 species occurs as an intermediate step before formation of 1:2 pseudooctahedral adducts. Spectra of the penta-co-ordinated species are reported and discussed; ligand-field calculations are in favour of a square pyramidal structure. © 1968.

引用

页码：2655 / +

页数：1

共 5 条

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[3] ABSORPTION SPECTRA OF TRANSITION GROUP COMPLEXES OF SULPHUR-CONTAINING LIGANDS
JORGENSEN, CK
[J]. JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1962, 24 (DEC): : 1571 - 1585
[4] JORGENSEN CK, 1963, INORGANIC COMPLEXES, P133
[5] METAL COMPLEXES OF LIGANDS CONTAINING SULPHUR SELENIUM OR TELLURIUM AS DONOR ATOMS
LIVINGSTONE, SE
[J]. QUARTERLY REVIEWS, 1965, 19 (04): : 386 - +

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