SYNTHESIS AND REACTION OF TRANS-DICHLOROBIS(ORTHO-PHENYLENEDIAMINE)RHODIUM(III) PERCHLORATE WITH SOME OXIDIZING-AGENTS

被引：3

作者：

FURUHASHI, A

ENDO, K

TAKAGI, S

YOSHINO, Y

机构：

[1] Department of Chemistry, Aoyama Gakuin University, 1-1 Morinosato-Aoyama, Atsugi

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1991年 / 64卷 / 01期

关键词：

D O I：

10.1246/bcsj.64.298

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new rhodium(III) complex with o-phenylenediamine, trans-[RhCl2{C6H4(NH2)2}2]ClO4 was synthesized and the reaction with oxidizing agents studied. Due to coordination with the rhodium(III) ion the o-phenylenediamine (opd) was greatly stabilized against oxidation and the complex was oxidized slowly by periodate via intermediate radical complex to bis(o-benzoquinone diimine)-dichlororhodium(III) complex which decomposed to the final products.

引用

页码：298 / 300

页数：3

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