FACTOR-F(430)-LIKE CATALYSIS OF [NIL] (L = DIANION OF 6,8,15,17-TETRAMETHYLDIBENZO[B,I][1,4,8,11]TETRAAZACYCLOTETRADECINE) IN THE REDUCTION OF ALKYL-HALIDES

被引：15

作者：

ARAI, T ^{[1
]}

KONDO, H ^{[1
]}

SAKAKI, S ^{[1
]}

机构：

[1] KUMAMOTO UNIV,FAC ENGN,DEPT APPL CHEM,KUROKAMI,KUMAMOTO 860,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1992年 / 18期

关键词：

D O I：

10.1039/dt9920002753

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reduction of alkyl halides by NaBH4 is efficiently catalysed by [NiL] (L = dianion of 6,8,15,17-tetramethyldibenzo[b,i] [1,4,8,11]tetraazacyclotetradecine), a plausible active species being [Ni(I)L]-.

引用

页码：2753 / 2754

页数：2

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