A VERSATILE NEW SYNTHESIS OF ORGANIC-COMPOUNDS WITH CHIRAL METHYL-GROUPS - STEREOCHEMISTRY OF PROTOLYTIC RHENIUM-CARBON BOND-CLEAVAGE IN CHIRAL ALKYL COMPLEXES (ETA5-C5H5)RE(NO)(PPH3)(R)

被引：56

作者：

OCONNOR, EJ

KOBAYASHI, M

FLOSS, HG

GLADYSZ, JA

机构：

[1] OHIO STATE UNIV,DEPT CHEM,COLUMBUS,OH 43210

[2] UNIV UTAH,DEPT CHEM,SALT LAKE CITY,UT 84112

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1987年 / 109卷 / 16期

关键词：

D O I：

10.1021/ja00250a014

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：4837 / 4844

页数：8

共 46 条

[1] STEREOCHEMISTRY OF 1,3-PROTON LOSS FROM A CHIRAL METHYL-GROUP IN BIOSYNTHESIS OF CYCLOARTENOL AS DETERMINED BY TRITIUM NUCLEAR MAGNETIC-RESONANCE SPECTROSCOPY [J].

ALTMAN, LJ ;

HAN, CY ;

BERTOLINO, A ;

HANDY, G ;

LAUNGANI, D ;

MULLER, W ;

SCHWARTZ, S ;

SHANKER, D ;

WOLF, WHD ;

YANG, F .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (10) :3235-3237

[2] SUBSTITUTION AND CLEAVAGE IN THE REACTION OF SOME BENZYL(CARBONYL)METAL COMPLEXES WITH TRIFLUOROACETIC-ACID [J].

ANDERSON, SN ;

COOKSEY, CJ ;

HOLTON, SG ;

JOHNSON, MD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (07) :2312-2318

[3] STEREOCHEMICAL EVIDENCE FOR PSEUDOROTATION IN THE REACTION OF A PHOSPHORIC MONOESTER [J].

BUCHWALD, SL ;

PLIURA, DH ;

KNOWLES, JR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (17) :4916-4922

[4] SYNTHESIS AND CHEMISTRY OF CHIRAL RHENIUM ACYLS (ETA-C5H5)RE(NO)(PPH3)(COR) [J].

BUHRO, WE ;

WONG, A ;

MERRIFIELD, JH ;

LIN, GY ;

CONSTABLE, AC ;

GLADYSZ, JA .

ORGANOMETALLICS, 1983, 2 (12) :1852-1859

[5] SYNTHESIS, STRUCTURE, AND REACTIVITY OF THE FORMALDEHYDE COMPLEX [(ETA-5-C5H5)RE(NO)(PPH3)(ETA-2-H2C=O)]+PF6- [J].

BUHRO, WE ;

GEORGIOU, S ;

FERNANDEZ, JM ;

PATTON, AT ;

STROUSE, CE ;

GLADYSZ, JA .

ORGANOMETALLICS, 1986, 5 (05) :956-965

[6] BIOSYNTHESIS OF ESTROGENS - THE STERIC MODE OF THE INITIAL C-19 HYDROXYLATION OF ANDROGENS BY HUMAN PLACENTAL AROMATASE [J].

CASPI, E ;

ARUNACHALAM, T ;

NELSON, PA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (23) :6987-6989

[7] MODE OF ENZYMIC OXYGENATION AT PRIMARY CARBON-ATOMS - STEREOCHEMISTRY OF HYDROXYLATION OF C-1 CHIRAL OCTANES BY PSEUDOMONAS-OLEOVORANS [J].

CASPI, E ;

PIPER, J ;

SHAPIRO, S .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1981, (03) :76-78

[8] STEREOCHEMISTRY OF THE TERMINATING METHYL-] METHYLENE ELIMINATION IN KAURENE BIOSYNTHESIS [J].

COATES, RM ;

KOCH, SC ;

HEGDE, S .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (10) :2762-2764

[9] ASYMMETRIC METHYL GROUPS AND MECHANISM OF MALATE SYNTHASE [J].

CORNFORTH, JW ;

REDMOND, JW ;

EGGERER, H ;

BUCKEL, W ;

GUTSCHOW, C .

NATURE, 1969, 221 (5187) :1212-+

[10]

CREIGHTON DJ, 1976, J BIOL CHEM, V251, P61

← 1 2 3 4 5 →