AN ASYMMETRIC-SYNTHESIS OF (+)-CRYPTONE

被引：10

作者：

HAWLEY, RC

SCHREIBER, SL

机构：

[1] Department of Chemistry. Yale University, New Haven, CT

来源：

SYNTHETIC COMMUNICATIONS | 1990年 / 20卷 / 08期

关键词：

D O I：

10.1080/00397919008052823

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A simple and practical method for the conversion of racemic cryptone into the (+)-enantiomer is reported. The procedure is expected to be general for 4-substituted cycloalkenones. Copyright © 1990 by Taylor & Francis Group. All rights reserved.

引用

页码：1159 / 1165

页数：7

共 8 条

[1] HYDROBORATION .68. CHIRAL SYNTHESIS VIA ORGANOBORANES .1. A SIMPLE PROCEDURE TO ACHIEVE PRODUCTS OF ESSENTIALLY 100-PERCENT OPTICAL PURITY IN HYDROBORATION OF ALKENES WITH MONOISOPINOCAMPHEYLBORANE - SYNTHESIS OF BORONIC ESTERS AND DERIVED PRODUCTS OF VERY HIGH ENANTIOMERIC PURITIES [J].

BROWN, HC ;

SINGARAM, B .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (06) :1797-1800

[2] ALPHA-METHOXY-ALPHA-TRIFLUOROMETHYLPHENYLACETIC ACID, A VERSATILE REAGENT FOR DETERMINATION OF ENANTIOMERIC COMPOSITION OF ALCOHOLS AND AMINES [J].

DALE, JA ;

DULL, DL ;

MOSHER, HS .

JOURNAL OF ORGANIC CHEMISTRY, 1969, 34 (09) :2543-&

[3] EXPEDITIOUS, STEREOCONTROLLED SYNTHESES OF RACEMIC AND NATURAL BRASILENOL THROUGH INTRAMOLECULAR ASYMMETRY TRANSFER - ABSOLUTE STEREOCHEMISTRY OF BRASILENOL [J].

GREENE, AE ;

SERRA, AA ;

BARREIRO, EJ ;

COSTA, PRR .

JOURNAL OF ORGANIC CHEMISTRY, 1987, 52 (06) :1169-1170

[4] CONFORMATIONAL CONTROL OF ENOLATE GEOMETRY - A SHORT SYNTHESIS OF GERMACRENE-D [J].

SCHREIBER, SL ;

HAWLEY, RC .

TETRAHEDRON LETTERS, 1985, 26 (48) :5971-5974

[5] CYCLOBUTENE BRIDGEHEAD OLEFIN ROUTE TO THE AMERICAN COCKROACH SEX-PHEROMONE, PERIPLANONE-B [J].

SCHREIBER, SL ;

SANTINI, C .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (14) :4038-4039

[6] ENANTIOSELECTIVE DEPROTONATION BY CHIRAL LITHIUM AMIDE BASES - ASYMMETRIC-SYNTHESIS OF TRIMETHYLSILYL ENOL ETHERS FROM 4-ALKYLCYCLOHEXANONES [J].

SHIRAI, R ;

TANAKA, M ;

KOGA, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (03) :543-545

[7]

SOFFER MD, 1963, TETRAHEDRON LETT, P389

[8] RAPID CHROMATOGRAPHIC TECHNIQUE FOR PREPARATIVE SEPARATIONS WITH MODERATE RESOLUTION [J].

STILL, WC ;

KAHN, M ;

MITRA, A .

JOURNAL OF ORGANIC CHEMISTRY, 1978, 43 (14) :2923-2925

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