KINETIC-THEORY OF DENSE FLUIDS .1.

被引:35
作者
EU, BC
机构
[1] Department of Chemistry, McGill University, Montreal, Que.
关键词
D O I
10.1016/0003-4916(79)90239-2
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
A kinetic theory of dense fluids is presented in this series of papers. The theory is based on a kinetic equation for subsystems which represents a subset of equations structurally invariant to the sizes of the subsystem that includes the Boltzmann equation as an element at the low density limit. There exists a H-function for the kinetic equation and the equilibrium solution is uniquely given by the canonical distribution functions for the subsystems comprising the entire system. The cluster expansion is discussed for the N-body collision operator appearing in the kinetic equation. The kinetic parts of transport coefficients are obtained by means of a moment method and their density expansions are formally obtained. The Chapman-Enskog method is discussed in the subsequent paper. © 1979.
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页码:187 / 229
页数:43
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