STUDIES ON CO[POLY(ETHYLENE TEREPHTHALATE-P-OXYBENZOATE)]THERMOTROPIC COPOLYESTER (I) - SYNTHESIS AND THERMOGRAVIMETRIC BEHAVIOR

被引：25

作者：

SHINN, TH ^{[1
]}

CHEN, JY ^{[1
]}

LIN, CC ^{[1
]}

机构：

[1] NATL CHIAO TUNG UNIV,INST APPL CHEM,HSINCHU,TAIWAN

来源：

JOURNAL OF APPLIED POLYMER SCIENCE | 1993年 / 47卷 / 07期

关键词：

D O I：

10.1002/app.1993.070470711

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A series of co[poly (ethylene terephthalate-p-oxybenzoate)] thermotropic copolyester was synthesized from various ratios of two different moieties of either poly(ethylene terephthalate) (PET) or its oligomer as moiety (II) with p-acetoxybenzoic acid as moiety (I) through the polycondensation process. The polymeric products obtained were then ground and subjected to solid-state polymerization under vacuum for various polymerization times. Thermogravimetric analysis (TGA) and the derivative thermogravimetric analysis (DTG) were performed with these samples obtained. Also, a commercial product, Eastman 10109, was analyzed in comparison with these samples. It was found that the copolyesters made of PET and of its oligomer in a p-oxybenzoate (POB):PET = 80:20 composition ratio and subjected to 8 and 4 h solid-state polymerization times, respectively, showed the most similar thermogravimetric behavior with Eastman 10109.

引用

页码：1233 / 1241

页数：9

共 6 条

[1] THE RECENT DEVELOPMENTS OF THERMOTROPIC LIQUID-CRYSTALLINE POLYMERS [J].