ASYMMETRIC ALKYLATION OF AROMATIC-ALDEHYDES BY DIETHYL ZINC IN THE PRESENCE OF (S)-N,N,N',N'-TETRAMETHYL-2,2'-DIAMINO-1,1'-BINAPHTHYL

被引：36

作者：

ROSINI, C ^{[1
]}

FRANZINI, L ^{[1
]}

IULIANO, A ^{[1
]}

PINI, D ^{[1
]}

SALVADORI, P ^{[1
]}

机构：

[1] CNR,CTR MACROMOLEC STEREODINATE & OTTICAMENTE ATT,DIPARTIMENTO CHIM & CHIM IND,I-56126 PISA,ITALY

来源：

TETRAHEDRON-ASYMMETRY | 1991年 / 2卷 / 05期

关键词：

D O I：

10.1016/S0957-4166(00)82120-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new chiral aprotic ligand 1, N,N,N',N'-tetramethyl-2,2'-diamino-1,1'-binaphthyl, having C2-symmetry structure, affords enantiomeric excesses up to 64% in the asymmetric alkylation of aromatic aldehydes by diethylzinc.

引用

页码：363 / 366

页数：4

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