TEMPERATURE AND SOLVENT DEPENDENT CATALYTIC TRANSFER HYDROGENOLYSIS IN AROMATIC-ALDEHYDES AND KETONES VIA AMMONIUM FORMATE

被引：14

作者：

RAM, S

SPICER, LD

机构：

[1] DUKE UNIV,MED CTR,DEPT BIOCHEM,PET FACIL,DURHAM,NC 27710

[2] DUKE UNIV,MED CTR,DEPT RADIOL,PET FACIL,DURHAM,NC 27710

来源：

SYNTHETIC COMMUNICATIONS | 1992年 / 22卷 / 18期

关键词：

D O I：

10.1080/00397919208021667

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Temperature control and solvent specification are used to reduce aromatic aldehydes and ketones to intermediate alcohols rather than methylene derivatives using HCO2NH4 as a catalytic hydrogen transfer agent. A mechanism for the catalytic reduction is proposed.

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页码：2673 / 2681

页数：9

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