MU-OXODIIRON(III) COMPLEXES OF PORPHYCENES

被引：40

作者：

LAUSMANN, M

ZIMMER, I

LEX, J

LUEKEN, H

WIEGHARDT, K

VOGEL, E

机构：

[1] UNIV COLOGNE,INST ORGAN CHEM,D-50939 COLOGNE,GERMANY

[2] RHEIN WESTFAL TH AACHEN,INST ANORGAN CHEM,W-5100 AACHEN,GERMANY

[3] RUHR UNIV BOCHUM,LEHRSTUHL ANORGAN CHEM 1,W-4630 BOCHUM,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 07期

关键词：

D O I：

10.1002/anie.199407361

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Far‐reaching analogies between μ‐oxodiiron(III) complexes of porphycenes and porphyrins with regard to physical, chemical, and structural properties are revealed by investigations of the new metallopor‐phycenes 1 (R  nPr, tBu). These are obtained by using standard methods for porphyrin chemistry. The Fe‐O‐Fe angle in 1 (R  nPr) differs widely (145°) from those of the metalloporphyrins (161–180°) and that of 1 (R  tBu; 179°) as a result of reduced steric interactions. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

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页码：736 / 739

页数：4

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