REACTION OF ALLYLMANGANESE(II) REAGENTS WITH ALDEHYDES

被引：5

作者：

AHN, Y ^{[1
]}

DOUBLEDAY, WW ^{[1
]}

COHEN, T ^{[1
]}

机构：

[1] UNIV PITTSBURGH,DEPT CHEM,PITTSBURGH,PA 15260

来源：

SYNTHETIC COMMUNICATIONS | 1995年 / 25卷 / 01期

基金：

美国国家卫生研究院;

关键词：

D O I：

10.1080/00397919508010786

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reaction of allylmanganese(II) reagents with aldehydes gives alcohols with high regioselectivity. The allylmanganese(II) reagents are prepared by transmetallation between manganese(II) chloride and allyllithium compounds which are generated from allyl phenyl sulfides by reductive lithiation.

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页码：33 / 41

页数：9

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