BIOTRANSFORMATION OF SESQUITERPENOIDS, (+)-AROMADENDRENE AND (-)-ALLOAROMADENDRENE BY GLOMERELLA-CINGULATA

被引：31

作者：

MIYAZAWA, M

UEMURA, T

KAMEOKA, H

机构：

[1] Department of Applied Chemistry, Faculty of Science and Engineering, Kinki University, Higashiosaka-shi, Osaka, 577, Kowakae

来源：

PHYTOCHEMISTRY | 1995年 / 40卷 / 03期

关键词：

BIOTRANSFORMATION; GLOMERELLA CINGULATA; (+)-AROMADENDRENE; (-)-ALLOAROMADENDRENE; (-)-10-ALPHA,13,14-TRIHYDROXYAROMADENDRANE; (-)-10-BETA,13,14-TRIHYDROXYALLOAROMADENDRANE; PLANT PATHOGENIC MICROORGANISM;

D O I：

10.1016/0031-9422(95)00352-8

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The biotransformation of(+)-aromadendrene and (-)-alloaromadendrene by a plant pathogenic microorganism, Glomerella cingulata, was investigated. Glomerella cingulata oxidized( +)-aromadendrene and (-)-alloaromadendrene at the double bond and at one of the geminal methyl groups on the cyclopropane ring regioselectivity to form triols which were hydroxylated at C-10, C-13 and C-14. The structures of the new compounds have been elucidated on the basis of their spectral data coupled with some chemical evidence.

引用

页码：793 / 796

页数：4

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