MORE ABOUT PI-SUCCINIMIDYL AND SIGMA-SUCCINIMIDYL RADICALS - RING-OPENING REACTIONS

被引：11

作者：

SKELL, PS

DAY, JC

SLANGA, JP

机构：

[1] Department of Chemistry, Pennsylvania State University, University Park, Pennsylvania

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1978年 / 17卷 / 07期

关键词：

D O I：

10.1002/anie.197805151

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

New ideas about the reactions of N‐halosuccinimides help to rationalize many apparently contradictory observations. The key hypothesis is that σ‐succinimidyl radicals undergo rapid and reversible cleavage whereas π radicals do not. (Figure Presented.) Copyright © 1978 by Verlag Chemie, GmbH, Germany

引用

页码：515 / 516

页数：2

共 12 条

[1]

CHILDS CR, 1961, J ORG CHEM, V26, P1630

[2] SUCCINIMIDYL RADICAL AS A CHAIN CARRIER - MECHANISM OF ALLYLIC BROMINATION [J].