CIS-METHYLDIAZENE

被引：17

作者：

CRAIG, NC

KLIEWER, MA

SHIH, NC

机构：

[1] Department of Chemistry, Oberlin College, Oberlin, Ohio

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1979年 / 101卷 / 09期

关键词：

D O I：

10.1021/ja00503a039

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

cis-Diazene (diimide) has been implicated as an intermediate in stereospecific reductions by in situ generated diazene1and in nitrogenase action on nitrogen.2This molecule and itsrather well-studied trans isomer3,4have been the objects of anumber of theoretical studies.5Yet, only fragmentary andinconclusive evidence has been reported for the direct observation of the cis isomer.6,7We now report the isolation of theclosest homologue of cis-diazene, cis-methyldiazene, and itsinfrared spectrum. Based on the assignment of this spectrum, we conclude that cis-diazene is yet to be observed. © 1979, American Chemical Society. All rights reserved.

引用

页码：2480 / 2482

页数：3

共 19 条

[1] INFRARED-SPECTRA AND VIBRATIONAL ASSIGNMENTS OF TRANS-CH3N-NH, CH3N-ND, CD3N-NH, AND CD3N-ND
ACKERMANN, MN
BURDGE, JJ
CRAIG, NC
[J]. JOURNAL OF CHEMICAL PHYSICS, 1973, 58 (01) : 203 - 215
[2] ACKERMANN MN, J PHYS CHEM
[3] NEAR-ULTRAVIOLET ABSORPTION-SPECTRUM OF DIIMIDE - RE-EXAMINATION
BACK, RA
WILLIS, C
RAMSAY, DA
[J]. CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1978, 56 (11): : 1575 - 1578
[4] INFRARED FREQUENCY EFFECTS OF LONE PAIR INTERACTIONS WITH ANTIBONDING ORBITALS ON ADJACENT ATOMS
BELLAMY, LJ
MAYO, DW
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1976, 80 (11) : 1217 - 1220
[5] V5 FUNDAMENTAL BANDS OF N2H2 AND N2D2
CARLOTTI, M
JOHNS, JWC
TROMBETTI, A
[J]. CANADIAN JOURNAL OF PHYSICS, 1974, 52 (04) : 340 - 344
[6] VIBRATIONAL-SPECTRA FOR TRANS-DIMETHYLDIAZENE-1,1,1-D3 (AZOMETHANE) - POTENTIAL FUNCTIONS FOR TRANS-DIMETHYLDIAZENE AND TRANS-METHYLDIAZENE
CRAIG, NC
ACKERMANN, MN
MACPHAIL, RA
[J]. JOURNAL OF CHEMICAL PHYSICS, 1978, 68 (01) : 236 - 246
[7] CHEMISTRY OF DIIMINE
HUNIG, S
MULLER, HR
THIER, W
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1965, 4 (04) : 271 - &
[8] PHOTOISOMERIZATION OF AZOMETHANE
HUTTON, RF
STEEL, C
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1964, 86 (04) : 745 - &
[9] INDIVIDUAL CH BOND STRENGTHS IN SIMPLE ORGANIC-COMPOUNDS - EFFECTS OF CONFORMATION AND SUBSTITUTION
MCKEAN, DC
[J]. CHEMICAL SOCIETY REVIEWS, 1978, 7 (03) : 399 - 422
[10] HYDROGENATION WITH DIIMIDE
MILLER, CE
[J]. JOURNAL OF CHEMICAL EDUCATION, 1965, 42 (05) : 254 - &

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