FARADAIC RECTIFICATION - AN AMENDED TREATMENT .2. EXPERIMENTAL VERIFICATION

被引：32

作者：

DELEEUWE, R

SLUYTERS.M

SLUYTERS, JH

机构：

[1] Laboratory of Analytical Chemistry, State University, Utrecht

来源：

ELECTROCHIMICA ACTA | 1969年 / 14卷 / 12期

关键词：

D O I：

10.1016/0013-4686(69)87015-5

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The conclusions arrived at in Part 11 of this series have been verified experimentally with Cd2+/Cd(Hg) in M NaClO 4, Fe2+/Fe3+ in M oxalate and Cd2+/Cd(Hg) in M KCl. The numerical method leads to values of the rate constant ksh that agree with those obtained by graphical extrapolation only if the reaction is rather irreversible. In the case of fast reactions the classical extrapolation method is shown to lead to serious errors. © 1969.

引用

页码：1183 / &

共 10 条

[1] FARADAIC RECTIFICATION AND ELECTRODE PROCESSES
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[2] FARADAIC RECTIFICATION - AN AMENDED TREATMENT
DELEEUWE, R
SLUYTERS.M
SLUYTERS, JH
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[3] FARADAIC RECTIFICATION AND ELECTRODE PROCESSES .4.
IMAI, H
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[4] GALVANOSTATIC SINGLE-PULSE AND COULOSTATIC IMPULSE METHODS FOR DETERMINATION OF RATE CONSTANTS OF ELECTRODE REACTIONS
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SLUYTERS, JH
[J]. ELECTROCHIMICA ACTA, 1967, 12 (12) : 1579 - &
[5] APPLICABILITY OF GALVANOSTATIC SINGLE-PULSE METHOD - CD2+/CD(HG) ELECTRODE IN M NA2SO4 NACIO4 AND KCL
KOOIJMAN, DJ
SLUYTERS, JH
[J]. ELECTROCHIMICA ACTA, 1967, 12 (06) : 693 - &
[6] KOOIJMAN DJ, 1966, ELECTROCHIM ACTA, V11, P1197
[7] FARADAIC RECTIFICATION AND ELECTRODE PROCESSES .2.
SENDA, M
DELARAY, P
IMAI, H
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1961, 65 (07) : 1253 - &
[8] SLUYTERSREHBACH M, 1963, RECL TRAV CHIM PAY B, V82, P535
[9] SLUYTERSREHBACH M, 1963, RECL TRAV CHIM PAY B, V82, P525
[10] SLUYTERSREHBACH.M, 1964, POLAROGRAPHY, P135

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