ELECTRONIC-SPECTRA OF M(BIPY)2+3 COMPLEX-IONS (M=FE, RU AND OS)

被引：138

作者：

FELIX, F ^{[1
]}

FERGUSON, J ^{[1
]}

GUDEL, HU ^{[1
]}

LUDI, A ^{[1
]}

机构：

[1] UNIV BERN,INST ANORGAN CHEM,CH-3000 BERN 9,SWITZERLAND

来源：

CHEMICAL PHYSICS LETTERS | 1979年 / 62卷 / 01期

关键词：

D O I：

10.1016/0009-2614(79)80432-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Linearly polarized absorption spectra of the complex ions M(bipy)2+3(M = Fe, Ru, Os) have been determined, together with the CD of the corresponding optical isomers at low temperature. The visible electronic spectra have been assigned to spin-allowed and spin-forbidden charge transfer as well as ligand-localized singlet to triplet transitions. The structure of the intense visible absorption band is due to two electronic transitions. © 1979.

引用

页码：153 / 157

页数：5

共 24 条

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