CYCLOPHANES .37. STRAIN-ACTIVATED FORMATION OF A TRIPLE-LAYERED PHANE

被引：4

作者：

HOPF, H ^{[1
]}

WITULSKI, B ^{[1
]}

BUBENITSCHEK, P ^{[1
]}

JONES, PG ^{[1
]}

机构：

[1] TECH UNIV BRAUNSCHWEIG, INST ANORGAN & ANALYT CHEM, W-3300 BRAUNSCHWEIG, GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1992年 / 31卷 / 08期

关键词：

D O I：

10.1002/anie.199210731

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In a simple, high‐yielding reaction the triple‐layered compound 2 is obtained from cyclophane 1 by Lewis acid catalyzed dimerization and subsequent aromatization of the central six‐membered ring. The reaction allows access to interesting multilayered arenes, and the intramolecular interactions of such π‐electron systems can now be studied. (Figure Presented.) Copyright © 1992 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1073 / 1074

页数：2

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