SIZE EFFECT IN THE PHOTOCHEMICAL GENERATION OF HYDROGEN FROM WATER BY COLLOIDAL FE2O3 PARTICLES

被引：36

作者：

CHATTERJEE, S

SARKAR, S

BHATTACHARYYA, SN

机构：

来源：

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY | 1993年 / 72卷 / 02期

关键词：

D O I：

10.1016/1010-6030(93)85027-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Colloidal Fe2O3 particles of various dimensions were prepared. Their crystal structure and optical properties were studied. These particles were used as photosensitizers for steady state water photolysis. The yield of H-2 generated is dependent on the particle size and the concentration of the colloids. The pH dependence is different for different particle sizes. The effects of methylviologen (MV2+) as an electron relay and CH3OH as a hole scavenger on the H-2 yield were also studied.

引用

页码：183 / 187

页数：5

共 28 条

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