BINAPHTHYL-SUBSTITUTED CHIRAL PHOSPHINES AND OXIDES FROM BINAPHTHOSPHOSPHOLES AND NUCLEOPHILES

被引：9

作者：

FABBRI, D

GLADIALI, S

DELUCCHI, O

机构：

[1] UNIV SASSARI,DIPARTIMENTO CHIM,VIA VIENNA 2,I-07100 SASSARI,ITALY

[2] UNIV VENEZIA,DIPARTIMENTO CHIM,I-30123 VENICE,ITALY

来源：

SYNTHETIC COMMUNICATIONS | 1994年 / 24卷 / 09期

关键词：

D O I：

10.1080/00397919408011728

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Binaphthophospholes 1 are the starting compounds for the synthesis of chiral phosphine oxides 3 or phosphines 4 via reaction of phospholium salts 2 with nucleophiles. The binaphthyl residue acts as a stereochemical probe for monitoring the integrity of the phosphorus stereocenter.

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页码：1271 / 1278

页数：8

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