MAGNETIC-FIELD EFFECTS UPON PHOTOREDOX REACTIONS OF BIFUNCTIONAL CHAIN MOLECULES CONTAINING ANILINO AND NITROAROMATIC CHROMOPHORES

被引：8

作者：

NAKAGAKI, R

MUTAI, K

NAGAKURA, S

机构：

[1] Institute for Molecular Science, Okazaki, 444, Myodaiji

来源：

CHEMICAL PHYSICS LETTERS | 1990年 / 167卷 / 05期

关键词：

D O I：

10.1016/0009-2614(90)85027-A

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Bichromophoric chain molecules, p-O2NC6H4O(CH2)12NBzC6H5 (Bz=*CX2C6H5, *C=12C or 13C, X=H or D), undergo two different intramolecular photoreactions involving the benzylic and methylene chain oxidations. The end product ratio for two competitive processes depends upon the magnetic field strength and nuclear magnetic moments within biradical intermediates. © 1990.

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页码：439 / 444

页数：6

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