SHPOLSKII FLUOROMETRY AS AN INDEPENDENT IDENTIFICATION METHOD TO UPGRADE ROUTINE HPLC ANALYSIS OF POLYCYCLIC AROMATIC-HYDROCARBONS

被引：11

作者：

MASTENBROEK, JWG

ARIESE, F

GOOIJER, C

VELTHORST, NH

HOFSTRAAT, JW

VANZEIJL, WJM

机构：

[1] FREE UNIV AMSTERDAM,DEPT GEN & ANALYT CHEM,DEBOELELAAN 1083,1081 HV AMSTERDAM,NETHERLANDS

[2] MINIST TRANSPORT & PUBL WORKS,DEPT PUBL WORKS,DIV TIDAL WATERS,2500 EX THE HAGUE,NETHERLANDS

来源：

CHEMOSPHERE | 1990年 / 21卷 / 03期

关键词：

D O I：

10.1016/0045-6535(90)90007-G

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

High Performance Liquid Chromatography combined with fluorescence detection is routinely used in the Dutch Water Quality Survey to determine the Polycyclic Aromatic Hydrocarbons (PAH) contents of marine sediment samples. In this paper Shpol'skii spectroscopy is utilized to ascertain the identity and the purity of the peaks in the chromatogram by collection of several eluting fractions and subsequent spectroscopic analysis. The low temperature Shpol'skii technique provides high-resolution fluorescence spectra of PAHs that can serve as fingerprints. Thus, information concerning peak purity was obtained and the number of components identified was roughly doubled. © 1990.

引用

页码：377 / 386

页数：10

共 6 条

[1] IDENTIFICATION OF MUTAGENIC METHYLBENZ[A]ANTHRACENE AND METHYLCHRYSENE ISOMERS IN NATURAL SAMPLES BY LIQUID-CHROMATOGRAPHY AND SHPOLSKII SPECTROMETRY [J].