INTER-MOLECULAR V-V TRANSFER IN THE VIBRATIONAL PREDISSOCIATION OF SOME VAN DER WAALS DIMERS

被引：2

作者：

BESWICK, JA ^{[1
]}

JORTNER, J ^{[1
]}

机构：

[1] TEL AVIV UNIV,DEPT CHEM,TEL AVIV,ISRAEL

来源：

CHEMICAL PHYSICS LETTERS | 1979年 / 65卷 / 02期

关键词：

D O I：

10.1016/0009-2614(79)87057-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We explore the consequences of intermolecular vibrational energy transfer in the vibrational predissociation (VP) of linear AB...CD van der Waals dimers. On the basis of our energy gap law for VP, which are supported by numerical model calculations, we demonstrate the efficiency of the V → V + T process, which will be amenable to experimental observation. © 1979.

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页码：240 / 245

页数：6

相关论文

共 16 条

[1]

ASHTON CJ, 1977, FARADAY DISCUSS, V62, P307

[2] PERPENDICULAR VIBRATIONAL PREDISSOCIATION OF T-SHAPED VANDERWAALS MOLECULES [J].

BESWICK, JA ;

JORTNER, J .

JOURNAL OF CHEMICAL PHYSICS, 1978, 69 (02) :512-518

[3] VIBRATIONAL PREDISSOCIATION OF TRIATOMIC VANDERWAALS MOLECULES [J].

BESWICK, JA ;

JORTNER, J .

JOURNAL OF CHEMICAL PHYSICS, 1978, 68 (05) :2277-2297

[4] MODEL FOR VIBRATIONAL PREDISSOCIATION OF VANDERWAALS MOLECULES [J].

BESWICK, JA ;

JORTNER, J .

CHEMICAL PHYSICS LETTERS, 1977, 49 (01) :13-18

[5]

BESWICK JA, 1978, INT C LASER CHEM EIN

[6]

BESWICK JA, UNPUBLISHED

[7]

BESWICK JA, 1978, J CHEM PHYS, V68, P4455

[8] THEORY OF BROADENING OF INFRARED-ABSORPTION SPECTRA OF HYDROGEN-BONDED SPECIES .2. COUPLING OF ANHARMONIC NU(XH) AND NU(XH..Y) MODES [J].

COULSON, CA ;

ROBERTSON, GN .

PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES, 1975, 342 (1630) :289-315

[9] THEORY OF BROADENING OF INFRARED-ABSORPTION SPECTRA OF HYDROGEN-BONDED SPECIES .1. [J].

COULSON, CA ;

ROBERTSON, GN .

PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1974, 337 (1609) :167-197

[10] ROLE OF VAN DER WAALS MOLECULES IN VIBRATIONAL-RELAXATION PROCESSES [J].

EWING, G .

CHEMICAL PHYSICS, 1978, 29 (03) :253-270