STRUCTURALLY DYNAMIC ORGANOMETAL COMPLEXES .1. SYNTHESIS AND STRUCTURAL DYNAMICS OF BIS(CYCLOPENTADIENYL)PHOSPHANEPALLADIUM COMPLEXES

被引：40

作者：

WERNER, H

KRAUS, HJ

机构：

[1] Institut Für Anorganische Chemie Der Universität, Würzburg

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1979年 / 18卷 / 12期

关键词：

D O I：

10.1002/anie.197909481

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A step on the way to palladocene could be the reaction shown below. The isolable compounds 1, LPMe3, P(iPr)3, PPh3, show a single sharp singlet for all ten cyclopentadienyl protons in the NMR spectrum. A fluxional structure, at least in solution, is deduced from the temperature dependence of the spectrum. (Figure Presented.) Copyright © 1979 by Verlag Chemie, GmbH, Germany

引用

页码：948 / 949

页数：2

共 5 条

[1]

COTTON FA, 1975, DYNAMIC NUCLEAR MAGN, P423

[2] SYNTHESIS AND PROPERTIES OF SEVERAL NEW MONO(PI-CYCLOPENTADIENYL)-NICKEL COMPLEXES [J].