CYCLOARTANE-TYPE SAPOGENINS AND THEIR GLYCOSIDES FROM CURCULIGO-ORCHIOIDES

被引：41

作者：

XU, JP ^{[1
]}

XU, RS ^{[1
]}

机构：

[1] ACAD SINICA,SHANGHAI INST MAT MED,SHANGHAI 200031,PEOPLES R CHINA

来源：

PHYTOCHEMISTRY | 1992年 / 31卷 / 07期

关键词：

CURCULIGO-ORCHIOIDES; HYPOXIDACEAE; CURCULIGENIN-B AND CURCULIGENIN-C; CURCULIGOSAPONIN K CURCULIGOSAPONIN-L AND CURCULIGOSAPONIN-M;

D O I：

10.1016/0031-9422(92)83298-D

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 [生物化学与分子生物学]; 081704 [应用化学];

摘要：

Several new cycloartane glycosides were isolated from rhizomes of Curculigo orchioides. Among them, two new triterpenoidal sapogenins named curculigenin B and C, which are common to three saponins, were formulated as (24S)-3-beta,11-alpha,16-beta,24-tetrahydroxycycloartane and 3-beta,11-alpha,16-beta-trihydroxycycloartane-24(25)-en, respectively, by H-1, C-13 NMR, 2D NMR analysis and chemical evidence. The structures of curculigosaponin K, L and M were elucidated on the basis of chemical methods and spectral data.

引用

页码：2455 / 2458

页数：4

共 6 条

[1]

KEIZUMI N, 1979, CHEM PHARM BULL, V27, P38

[2]

RICCIO R, 1985, GAZZ CHIM ITAL, V115, P405

[3]

DETERMINATION OF ABSOLUTE-CONFIGURATION OF A SECONDARY HYDROXY GROUP IN A CHIRAL SECONDARY ALCOHOL USING GLYCOSIDATION SHIFTS IN C-13 NUCLEAR MAGNETIC-RESONANCE SPECTROSCOPY [J].

SEO, S ;

TOMITA, Y ;

TORI, K ;

YOSHIMURA, Y .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (11) :3331-3339

[4]

XU JP, 1992, UNPUB PLANTA MED

[5]

XU JP, 1992, UNPUB PHYTOCHEMISTRY

[6]

1979, DICT CHINESE TRADITI, P1363

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