THERMAL AND PHOTOCHEMICAL-REACTIONS OF CHROMIUM CARBENES AND SULFUR YLIDES - AN EFFICIENT ENTRY TO FUNCTIONALIZED VINYL ETHERS

被引：19

作者：

ALCAIDE, B ^{[1
]}

DOMINGUEZ, G ^{[1
]}

RODRIGUEZLOPEZ, J ^{[1
]}

SIERRA, MA ^{[1
]}

机构：

[1] UNIV COMPLUTENSE MADRID,FAC QUIM,DEPT QUIM ORGAN 1,E-28040 MADRID,SPAIN

来源：

ORGANOMETALLICS | 1992年 / 11卷 / 06期

关键词：

D O I：

10.1021/om00042a001

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The photochemical reaction of pentacarbonylalkoxychromium(0) carbene complexes and stabilized sulfur ylides affords vinyl ethers with moderate stereoselectivity. The thermal reaction of the above reagents also produces vinyl ethers, but some differences in yields and stereoselectivity have been observed.

引用

页码：1979 / 1981

页数：3

共 24 条

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