NOVEL SEQUENCE WITH INCOMMENSURATE SA PHASES IN A NEW DIMESOGENIC LIQUID-CRYSTAL

被引:108
作者
HARDOUIN, F [1 ]
ACHARD, MF [1 ]
JIN, JL [1 ]
SHIN, JW [1 ]
YUN, YK [1 ]
机构
[1] KOREA UNIV,COLL SCI,DEPT CHEM,SEOUL 136701,SOUTH KOREA
来源
JOURNAL DE PHYSIQUE II | 1994年 / 4卷 / 04期
关键词
D O I
10.1051/jp2:1994152
中图分类号
O3 [力学];
学科分类号
08 ; 0801 ;
摘要
We present differential scanning calorimetry, optical and X-ray diffraction measurements for a new dimesogenic liquid crystal compound (KI5). The rich polymorphism of this compound includes new smectic phases and rare phase transitions. In particular the first observation in a pure compound of two incommensurate SA phases as well as cholesteric and helical smectic phases (TGB and SC* phases) are reported. We discuss this observation in terms of the dual peculiar structural character of the molecule : a polyphilic and dimesogenic system including the concept of the central flexible spacer.
引用
收藏
页码:627 / 643
页数:17
相关论文
共 36 条
[1]  
AGUILERA C, 1984, POLYM B, V12, P383
[2]   INCOMMENSURATE SMECTIC-A PHASE IN THE GENERAL-MODEL OF FRUSTRATED SMECTIC PHASES [J].
BAROIS, P .
PHYSICAL REVIEW A, 1986, 33 (05) :3632-3634
[3]   NEW CRITICAL-POINTS IN FRUSTRATED SMECTICS [J].
BAROIS, P ;
PROST, J ;
LUBENSKY, TC .
JOURNAL DE PHYSIQUE, 1985, 46 (03) :391-399
[4]  
BAROIS P, 1981, J PHYS LETT-PARIS, V42, pL107, DOI 10.1051/jphyslet:01981004205010700
[5]  
BAROIS P, 1992, SOLITONS LIQUID CRYS, P191
[6]  
BLINOV LM, 1993, J PHYS II, V3, P1121, DOI 10.1051/jp2:1993187
[7]   MODEL COMPOUNDS OF MAIN-CHAIN THERMOTROPIC NEMATIC POLYESTERS [J].
BLUMSTEIN, RB ;
POLIKS, MD ;
STICKLES, EM ;
BLUMSTEIN, A ;
VOLINO, F .
MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1985, 129 (04) :375-407
[8]   SYNTHESIS OF MODEL COMPOUNDS OF THE NEMATIC POLYESTER POLY(2,2'-DIMETHYL-4,4'-DIOXYAZOXY-BENZENEDODECANEDIOYL) [J].
BLUMSTEIN, RB ;
STICKLES, EM .
MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1982, 82 (05) :151-159
[9]   MESOPHASIC PROPERTIES OF LOW-MOLECULAR WEIGHT MODEL COMPOUNDS CONTAINING 2 RIGID GROUPS CONNECTED BY A FLEXIBLE SPACER [J].
BUGLIONE, JA ;
ROVIELLO, A ;
SIRIGU, A .
MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1984, 106 (1-2) :169-185
[10]   EFFECT OF MOLECULAR-STRUCTURE ON MESOMORPHISM .18. TWIN DIMERS HAVING METHYLENE, ETHYLENE-OXIDE AND SILOXANE SPACERS [J].
CREED, D ;
GROSS, JRD ;
SULLIVAN, SL ;
GRIFFIN, AC ;
HOYLE, CE .
MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1987, 149 :185-193