MOLECULAR-STRUCTURES, ELECTROCHEMICAL AND SPECTROSCOPICAL PROPERTIES OF DICHLORODICARBONYLBIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II) AND DICHLORODICARBONYLBIS(TRIPHENYLARSINE)RUTHENIUM(II)

被引：26

作者：

BATISTA, AA

ZUKERMANSCHPECTOR, J

PORCU, OM

QUEIROZ, SL

ARAUJO, MP

OLIVA, G

SOUZA, DHF

机构：

[1] UNIV SAO PAULO, DEPT FIS & CIENCIA MAT, BR-13560 SAO CARLOS, SP, BRAZIL

[2] UNIV ESTADUAL PAULISTA, DEPT CIENCIAS, ILHA SOLTEIRA, SP, BRAZIL

来源：

POLYHEDRON | 1994年 / 13卷 / 04期

关键词：

D O I：

10.1016/S0277-5387(00)84747-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The cct isomers [RuCl2(CO)2(PPh3)2] (1) and [RuCl2(CO)2(AsPh3)2] (2) were synthesized from [RuCl3(PPh3)2DMA]DMA and [RuCl3(AsPh3)2DMA]DMA, respectively. The complexes were characterized by elemental analysis, IR and UV-vis spectroscopy and their molecular structures were found to be cis-cis-trans isomers by X-ray crystallography. Cyclic voltammetry data show that the triphenylphosphine stabilizes better the ruthenium (II) complex than the triphenylarsine ligand.

引用

页码：689 / 693

页数：5

共 20 条

[1] TRANS-INFLUENCE - ITS MEASUREMENT AND SIGNIFICANCE
APPLETON, TG
CLARK, HC
MANZER, LE
[J]. COORDINATION CHEMISTRY REVIEWS, 1973, 10 (3-4) : 335 - 422
[2] STRUCTURE OF BIS(DIMETHYLPHENYLPHOSPHINE)(ETHYLENE)(CARBONYL) DICHLORORUTHENIUM(II), RUCL2(CO)(C2H4)(P(CH3)2(C6H5))2, A 6-COORDINATE D6 COMPLEX CONTAINING ETHYLENE AS A LIGAND
BROWN, LD
BARNARD, CFJ
DANIELS, JA
MAWBY, RJ
IBERS, JA
[J]. INORGANIC CHEMISTRY, 1978, 17 (10) : 2932 - 2935
[3] CRYSTAL AND MOLECULAR-STRUCTURE OF ACETATOCARBONYL(N-P-TOLYLFORMIDOYL)BIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II)
CLARK, GR
WATERS, JM
WHITTLE, KR
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1975, (23): : 2556 - 2560
[4] HYDROFORMYLATION OF ALKENES BY USE OF RHODIUM COMPLEX CATALYSTS
EVANS, D
OSBORN, JA
WILKINSON, G
[J]. JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1968, (12): : 3133 - +
[5] HOMOGENEOUS HYDROGENATION AND HYDROFORMYLATION USING RUTHENIUM COMPLEXES
EVANS, D
OSBORN, JA
JARDINE, FH
WILKINSON, G
[J]. NATURE, 1965, 208 (5016) : 1203 - +
[6] FAHEY DR, 1978, J ORG CHEM, V88, P801
[7] INFLUENCE PARAMETERS - QUANTITATIVE CHARACTERISTIC OF CAPACITY OF LIGANDS TO EXERT MUTUAL INFLUENCE
GOFMAN, MM
NEFEDOV, VI
[J]. INORGANICA CHIMICA ACTA, 1978, 28 (01) : 1 - 17
[8] RECOMMENDATIONS ON REPORTING ELECTRODE-POTENTIALS IN NON-AQUEOUS SOLVENTS
GRITZNER, G
KUTA, J
[J]. PURE AND APPLIED CHEMISTRY, 1982, 54 (08) : 1527 - 1532
[9] JAMES BR, 1973, HOMOGENEOUS HYDROGEN, P101
[10] JOHNSON CK, 1965, ORNL3794 REP

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