ELECTROCHEMICAL POLYMERIZATION OF INDOLE

被引：39

作者：

BILLAUD, D

MAAROUF, EB

HANNECART, E

机构：

[1] UNIV MOHAMED LER,CHIM ORGAN PHYS LAB,OUJDA,MOROCCO

[2] SOC SOLVAY & CIE,B-1120 BRUSSELS,BELGIUM

来源：

POLYMER | 1994年 / 35卷 / 09期

关键词：

POLYINDOLE; CONDUCTING POLYMER; ELECTROCHROMIC PROPERTIES;

D O I：

10.1016/0032-3861(94)90999-7

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Electrochemical oxidation of indole, C8NH7, in a non-aqueous medium, such as a solution of LiClO4 or LiBF4, dissolved in acetonitrile, leads to the formation of polyindole, an air stable conducting polymer that exhibits electrochromic properties. The room temperature electrical conductivity, in the range 5 x 10(-3)-8 x 10(-2) S cm-1, depends slightly on the nature of the counterion.

引用

页码：2010 / 2011

页数：2

共 8 条

[1] A POLYMER ELECTRODE WITH VARIABLE CONDUCTIVITY - POLYPYRROLE [J].

DIAZ, AF ;

CASTILLO, JI .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1980, (09) :397-398

[2]

LAZZARONI R, 1987, SYNTHETIC MET, V21, P198

[3]

MAAROUF EB, 1989, THESIS U NANCY

[4]

MAAROUF EB, IN PRESS MAT RES B

[5]

Skotheim T. A., 1986, HDB CONDUCTING POLYM

[6] NEW ELECTROCHEMICALLY GENERATED ORGANIC CONDUCTING POLYMERS [J].

TOURILLON, G ;

GARNIER, F .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1982, 135 (01) :173-178

[7]

Van de Pauw L.J., 1958, PHILIPS RES REP, V13, P1

[8] SUBSTITUENT EFFECTS IN THE ELECTROPOLYMERIZATION OF AROMATIC HETEROCYCLIC-COMPOUNDS [J].

WALTMAN, RJ ;

DIAZ, AF ;

BARGON, J .

JOURNAL OF PHYSICAL CHEMISTRY, 1984, 88 (19) :4343-4346

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