LUMINESCENCE QUENCHING BEHAVIOR OF AN OXYGEN SENSOR-BASED ON A RU(II) COMPLEX DISSOLVED IN POLYSTYRENE

被引：191

作者：

HARTMANN, P ^{[1
]}

LEINER, MJP ^{[1
]}

LIPPITSCH, ME ^{[1
]}

机构：

[1] KARL FRANZENS UNIV GRAZ,INST PHYS EXPTL,A-8010 GRAZ,AUSTRIA

来源：

ANALYTICAL CHEMISTRY | 1995年 / 67卷 / 01期

关键词：

D O I：

10.1021/ac00097a015

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Chemically homogeneous polymer layers loaded with oxygen-quenchable luminescent dyes may lead to promising applications for optical oxygen sensing. In this work, luminescence quenching of tris(4,7'-diphenyl-1-1,10'phenanthroline)Ru(II) perchlorate, dissolved in a polystyrene layer, has been investigated. Although the dye appears to be molecularly dispersed in this glassy polymer, the Stern-Volmer intensity plot is nonlinear and the luminescence decay is not single exponential. This can be attributed to a spatial disorder in the polymer structure, which is likely to determine the excited state properties. It is shown that an analysis of intensity quenching and luminescence lifetime data based on a multicomponent approach, which was previously developed for dyes in chemically heterogeneous silica matrices, can also be applied to this polymer. Quenching is shown to be dynamic in nature. Some features of polystyrene-based optical oxygen sensors having an enhanced dye concentration are pointed out.

引用

页码：88 / 93

页数：6

共 35 条

[1]

Alexander L. E., 1979, XRAY DIFFRACTION MET

[2] DETERMINATION OF OXYGEN CONCENTRATIONS BY LUMINESCENCE QUENCHING OF A POLYMER-IMMOBILIZED TRANSITION-METAL COMPLEX [J].

BACON, JR ;

DEMAS, JN .

ANALYTICAL CHEMISTRY, 1987, 59 (23) :2780-2785

[3] SURFACE PHOTOCHEMISTRY - THE EFFECT OF SURFACE MODIFICATION ON THE PHOTOPHYSICS OF NAPHTHALENE AND PYRENE ADSORBED ON SILICA-GEL [J].

BAUER, RK ;

DEMAYO, P ;

NATARAJAN, LV ;

WARE, WR .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1984, 62 (07) :1279-1286

[4] PHOTOPHYSICS AND PHOTOCHEMISTRY OF OXYGEN SENSORS BASED ON LUMINESCENT TRANSITION-METAL COMPLEXES [J].

CARRAWAY, ER ;

DEMAS, JN ;

DEGRAFF, BA ;

BACON, JR .

ANALYTICAL CHEMISTRY, 1991, 63 (04) :337-342

[5] LUMINESCENCE QUENCHING MECHANISM FOR MICROHETEROGENEOUS SYSTEMS [J].

CARRAWAY, ER ;

DEMAS, JN ;

DEGRAFF, BA .

ANALYTICAL CHEMISTRY, 1991, 63 (04) :332-336

[6] LUMINESCENT METAL-COMPLEXES .1. TRIS-CHELATES OF SUBSTITUTED 2,2'-BIPYRIDYLS WITH RUTHENIUM(II) AS DYES FOR LUMINESCENT SOLAR COLLECTORS [J].

COOK, MJ ;

LEWIS, AP ;

MCAULIFFE, GSG ;

SKARDA, V ;

THOMSON, AJ ;

GLASPER, JL ;

ROBBINS, DJ .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1984, (08) :1293-1301

[7] DESIGN AND APPLICATIONS OF HIGHLY LUMINESCENT TRANSITION-METAL COMPLEXES [J].

DEMAS, JN ;

DEGRAFF, BA .

ANALYTICAL CHEMISTRY, 1991, 63 (17) :A829-A837

[8]

DEMAS JN, 1971, J PHYS CHEM-US, V75, P991, DOI 10.1021/j100678a001

[9]

DREXHAGE KH, 1977, DYE LASERS TOPICS AP, V1

[10] EXPOSURE OF TRYPTOPHANYL RESIDUES IN PROTEINS - QUANTITATIVE-DETERMINATION BY FLUORESCENCE QUENCHING STUDIES [J].

EFTINK, MR ;

GHIRON, CA .

BIOCHEMISTRY, 1976, 15 (03) :672-680

← 1 2 3 4 →