TRANSIENT POLARIZATION 4-PHOTON NON-CONDON SPECTROSCOPY OF ELECTRONIC-TRANSITIONS IN COMPLEX-MOLECULES

被引：8

作者：

FAINBERG, B ^{[1
]}

RICHERT, R ^{[1
]}

GOLDBERG, SY ^{[1
]}

HUPPERT, D ^{[1
]}

机构：

[1] TEL AVIV UNIV,SCH CHEM,RAYMOND & BEVERLY SACKLER FAC EXACT SCI,IL-69978 TEL AVIV,ISRAEL

来源：

JOURNAL OF LUMINESCENCE | 1994年 / 60-1卷

关键词：

D O I：

10.1016/0022-2313(94)90257-7

中图分类号：

O43 [光学];

学科分类号：

070207 ; 0803 ;

摘要：

We show both theoretically and experimentally that resonance transient grating spectroscopy (RTGS) is a good method for the investigation of ultrafast solvation dynamics of large probe molecules in solutions. We have studied the solvation dynamics of LDS 750 in many solvents in a broad time range by RTGS and by induced optical Kerr effect spectroscopy. We propose a new method for the investigation of non-Condon effects in solvation: transient polarization four-photon spectroscopy.

引用

页码：709 / 712

页数：4

共 8 条

[1] NON-MARKOVIAN DEPHASING OF MOLECULES IN SOLUTION MEASURED WITH 3-PULSE FEMTOSECOND PHOTON-ECHOES [J].

BIGOT, JY ;

PORTELLA, MT ;

SCHOENLEIN, RW ;

BARDEEN, CJ ;

MIGUS, A ;

SHANK, CV .

PHYSICAL REVIEW LETTERS, 1991, 66 (09) :1138-1141

[2]

FAINBERG B, 1993, ISRAEL J CHEM, V33, P225

[3] MICROWAVE ABSORPTION AND MOLECULAR STRUCTURE IN LIQUIDS .62. 3 DIELECTRIC DISPERSION REGIONS OF NORMAL PRIMARY ALCOHOLS [J].

GARG, SK ;

SMYTH, CP .

JOURNAL OF PHYSICAL CHEMISTRY, 1965, 69 (04) :1294-&

[4]

GOLDBERG SY, IN PRESS CHEM PHYS

[5] PICOSECOND SOLVATION DYNAMICS OF COUMARIN-153 - THE IMPORTANCE OF MOLECULAR ASPECTS OF SOLVATION [J].

MARONCELLI, M ;

FLEMING, GR .

JOURNAL OF CHEMICAL PHYSICS, 1987, 86 (11) :6221-6239

[6]

RICHERT R, 1993, IN PRESS 26TH JER S

[7] FEMTOSECOND SOLVATION DYNAMICS IN ACETONITRILE - OBSERVATION OF THE INERTIAL CONTRIBUTION TO THE SOLVENT RESPONSE [J].

ROSENTHAL, SJ ;

XIE, XL ;

DU, M ;

FLEMING, GR .

JOURNAL OF CHEMICAL PHYSICS, 1991, 95 (06) :4715-4718

[8]

WIERSMA DA, 1993, ULTRAFAST PHENOMENA, V8, P611

← 1 →