THERMAL DECOMPOSITION OF NITROSYL PERCHLORATE AND NITRYL PERCHLORATE .I. MECHANISM OF DECOMPOSITION

被引：5

作者：

GLASNER, A

PELLY, I

STEINBER.M

机构：

[1] Department of Inorganic and Analytical Chemistry, The Hebrew University, Jerusalem

来源：

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY | 1969年 / 31卷 / 11期

关键词：

D O I：

10.1016/0022-1902(69)80322-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The thermal decomposition of NOClO4 (powder, or fragments of pressed pellets) and of NO2ClO4 (granules) has been studied gasometrically and by X-ray diffraction. During the decomposition of NOClO4, NO2ClO4 is formed as an intermediate. The following mechanism is suggested for the decomposition of NOClO4: NOCl4→ClO3+NO2, 3NOClO4+ClO3→ 1 2+3NO2ClO4, 3NO2ClO4→3ClO2+3NO2+3o2. NO2ClO4 is partly reduced to NOClO4. Independently of the initial sample, the reaction mixture will contain both perchlorates. © 1969.

引用

页码：3395 / &

共 13 条

[1] THERMAL DECOMPOSITION OF NITRYL PERCHLORATE [J].