GRAFTING ONTO WOOL .6. EFFECT OF AMINES IN CERIC ION-INITIATED GRAFTING OF POLYVINYL ACETATE)

被引：28

作者：

MISRA, BN

KAUR, I

DOGRA, R

机构：

[1] Department of Chemistry, Himachal Pradesh University, Simla

来源：

JOURNAL OF APPLIED POLYMER SCIENCE | 1979年 / 24卷 / 07期

关键词：

D O I：

10.1002/app.1979.070240702

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Poly(vinyl acetate) has been graft copolymerized onto Himachali wool in the presence of ceric ammonium nitrate alone and in presence of amines in aqueous medium under a wide variety of reaction conditions. Nitric acid was found to catalyze the graft copolymerization. Maximum grafting under optimum conditions has been determined. Several grafting experiments were carried out in presence of triethylamine and triethanolamine. Both amines were found to reduce the extent of grafting. The decrease in the percent grafting in presence of amines has been explained in terms of a chain‐transfer mechanism. Copyright © 1979 John Wiley & Sons, Inc.

引用

收藏

页码：1595 / 1602

页数：8

相关论文

共 17 条

[1] GRAFTING ONTO WOOL .4. INTERACTION OF POLYMER RADICALS IN VISCOUS MEDIA OF WOOL FIBERS [J].

ARAI, K ;

SHIMIZU, M ;

SHIMADA, M .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1973, 11 (12) :3271-3282

[2] GRAFTING ONTO WOOL .2. BPO-INITIATED GRAFTING OF POLYSTYRENE [J].

CHANDEL, PS ;

MISRA, BN .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1977, 15 (07) :1549-1554

[3] GRAFT COPOLYMERIZATION ONTO PROTEIN BY CERIC ION METHOD . STUDIES ON GRAFTING SITE [J].

IMAI, Y ;

IWAKURA, Y .

JOURNAL OF APPLIED POLYMER SCIENCE, 1967, 11 (08) :1529-&

[4] CEIV INITIATED GRAFT POLYMERIZATION OF METHYL METHACRYLATE ON WOOL FIBRES [J].

KANTOUCH, A ;

HEBEISH, A ;

BENDAK, A .

EUROPEAN POLYMER JOURNAL, 1971, 7 (02) :153-&

[5] ACID CATALYZED GRAFTING OF MONOMERS TO WOOL [J].

KENYON, RS ;

GARNETT, JL .

JOURNAL OF POLYMER SCIENCE PART C-POLYMER LETTERS, 1973, 11 (10) :651-654

[6] A NEW METHOD FOR FORMING VINYL POLYMERS IN WOOL [J].

LIPSON, M .

NATURE, 1949, 164 (4170) :576-576

[7]

MADARAS GW, 1954, J SOC DYERS COLOUR, V70, P112

[8] A NEW METHOD FOR THE PREPARATION OF GRAFT COPOLYMERS - POLYMERIZATION INITIATED BY CERIC ION REDOX SYSTEMS [J].

MINO, G ;

KAIZERMAN, S .

JOURNAL OF POLYMER SCIENCE, 1958, 31 (122) :242-243

[9] GRAFTING ONTO WOOL .1. CERIC ION-INITIATED GRAFTING OF POLY(METHYL ACRYLATE) ONTO WOOL [J].

MISRA, BN ;

CHANDEL, PS .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1977, 15 (07) :1545-1548

[10] GRAFTING ONTO WOOL .3. GRAFT CO-POLYMERIZATION OF POLYVINYL ACETATE) BY USE OF FENTONS REAGENT AS INITIATOR [J].

MISRA, BN ;

CHANDEL, PS ;

DOGRA, R .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1978, 16 (08) :1801-1805