THE SYNTHESIS AND REACTIVITY OF SOME PEROXO COMPLEXES OF MOLYBDENUM(VI) AND TUNGSTEN(VI)

被引：13

作者：

ISLAM, MS

UDDIN, MM

机构：

[1] Department of Chemistry, Rajshahi University, Rajshahi

来源：

POLYHEDRON | 1992年 / 11卷 / 22期

关键词：

D O I：

10.1016/S0277-5387(00)83595-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Some new peroxo complexes of molybdenum(VI) and tungsten(VI) containing organic dibasic acids and heterocyclic amines have been prepared and characterized. The complexes have the composition [M(O)(O2)(acid) . L], where M = molybdenum(VI) or tungsten(VI), acid = dianion of diphenic acid (da) or homophthalic acid (hp) and L = 2,2'-bipyridine (bpy) or 1,10-phenanthroline (phen). The complexes did not oxidize allyl alcohol, but oxidized triphenylphosphine and triphenylarsine to their respective oxides.

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页码：2913 / 2916

页数：4

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