SYNTHESIS AND PROTONATION OF THE DITHIOFORMATO COMPLEX OSH(ETA(2)-S2CH)(CO)(PIPR(3))(2)

被引：37

作者：

ALBENIZ, MJ ^{[1
]}

BUIL, ML ^{[1
]}

ESTERUELAS, MA ^{[1
]}

LOPEZ, AM ^{[1
]}

ORO, LA ^{[1
]}

ZEIER, B ^{[1
]}

机构：

[1] UNIV ZARAGOZA,CSIC,INST CIENCIA MAT ARAGON,DEPT QUIM ORGAN,E-50009 ZARAGOZA,SPAIN

来源：

ORGANOMETALLICS | 1994年 / 13卷 / 09期

关键词：

D O I：

10.1021/om00021a058

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of the complex OsHCl(CO)-(PiPr(3))(2) (1) With nBuLi in hexane affords OsH2(eta(2)-CH2=CHEt)(CO)(PiPr(3))(2) (2) which reacts with CS2 to give OsH(eta(2)-S2CH)(CO)(PiPr(3))(2) (3) The reaction of 3 with HBF4.OEt(2) Leads to two different derivatives depending upon the nature of the solvent used. The dihydrogen compound [Os(eta(2)-S2CH)(eta(2)-H-2)(CO)(PiPr(3))(2)]-BF4 (4) is formed in dichloromethane-d(2), while the methanedithiolate complex [OsH(eta(2)-S2CH2)(CO)(PiPr(3))(2)]-BF4 (5) is obtained in diethyl ether.

引用

页码：3746 / 3748

页数：3

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