THE MAGNETIC-PROPERTIES OF THE SYNTHETIC LANGBEINITE KBACR2(PO4)3

被引：39

作者：

BATTLE, PD ^{[1
]}

GIBB, TC ^{[1
]}

NIXON, S ^{[1
]}

HARRISON, WTA ^{[1
]}

机构：

[1] RUTHERFORD APPLETON LAB,DIV NEUTRON,DIDCOT OX11 0QX,OXON,ENGLAND

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 1988年 / 75卷 / 01期

关键词：

CRYSTALS - Structure - SOLIDS - Magnetic Properties - SPECTROSCOPY; MOSSBAUER; -; Applications;

D O I：

10.1016/0022-4596(88)90299-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The crystal and magnetic structures of the synthetic langbeinite KBaCr//2(PO//4)//3 at 1. 8 K have been determined from neutron powder diffraction data. The two crystallographically distinct Cr**3** plus sublattices in the cubic structure are aniferromagnetically coupled with an ordered magnetic moment of 2. 4(2) mu //B per Cr**3** plus . Mossbauer spectroscopy has been used to determine the Neel temperature of an **5**7Fe-doped sample at 12 K. The effective magnetic moment in the paramagnetic phase has been determined to be 3. 84 mu //B per Cr**3** plus ion.

引用

页码：21 / 29

页数：9

共 13 条

[1] STRUCTURAL PHASE-TRANSITIONS IN LANGBEINITES - AN ELECTRON-PARAMAGNETIC-RES STUDY [J].

BABU, DS ;

SASTRY, GS ;

SASTRY, MD ;

DALVI, AGI .

JOURNAL OF PHYSICS C-SOLID STATE PHYSICS, 1984, 17 (24) :4245-4253

[2] STUDY OF THE MAGNETIC-PROPERTIES OF IRON(III) MOLYBDATE, BY SUSCEPTIBILITY, MOSSBAUER, AND NEUTRON-DIFFRACTION TECHNIQUES [J].

BATTLE, PD ;

CHEETHAM, AK ;

LONG, GJ ;

LONGWORTH, G .

INORGANIC CHEMISTRY, 1982, 21 (12) :4223-4228

[3] THE STRUCTURE AND MAGNETIC-PROPERTIES OF CHROMIUM(III) MOLYBDATE [J].

BATTLE, PD ;

CHEETHAM, AK ;

HARRISON, WTA ;

POLLARD, NJ ;

FABER, J .

JOURNAL OF SOLID STATE CHEMISTRY, 1985, 58 (02) :221-225

[4] THE CRYSTAL-STRUCTURE AND MAGNETIC-PROPERTIES OF THE SYNTHETIC LANGBEINITE KBAFE2(PO4)3 [J].

BATTLE, PD ;

CHEETHAM, AK ;

HARRISON, WTA ;

LONG, GJ .

JOURNAL OF SOLID STATE CHEMISTRY, 1986, 62 (01) :16-25

[5] ANTIFERROMAGNETIC STRUCTURE IN CR2O3 [J].

BROCKHOUSE, BN .

JOURNAL OF CHEMICAL PHYSICS, 1953, 21 (05) :961-962

[6] STUDY OF ANHYDROUS IRON(III) SULFATE BY MAGNETIC-SUSCEPTIBILITY, MOSSBAUER, AND NEUTRON-DIFFRACTION TECHNIQUES [J].

LONG, GJ ;

LONGWORTH, G ;

BATTLE, P ;

CHEETHAM, AK ;

THUNDATHIL, RV ;

BEVERIDGE, D .

INORGANIC CHEMISTRY, 1979, 18 (03) :624-632

[7] LANGBEINITE TYPE MONOPHOSPHATES [J].

MASSE, R .

BULLETIN DE LA SOCIETE FRANCAISE MINERALOGIE ET DE CRISTALLOGRAPHIE, 1972, 95 (03) :405-&

[8]

NEEL L, 1948, ANN PHYS-PARIS, V3, P137

[9] A PROFILE REFINEMENT METHOD FOR NUCLEAR AND MAGNETIC STRUCTURES [J].

RIETVELD, HM .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1969, 2 :65-&

[10]

THOMAS MW, 1978, ACTA CRYSTALLOGR A, V34, pS351

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