FLUORESCENCE EXCITATION SPECTRUM OF THE 1AU (NPI-]) ]-1AG (O-O) BAND OF OXALYL FLUORIDE IN A PULSED SUPERSONIC FREE JET

被引：75

作者：

LIVERMAN, MG

BECK, SM

MONTS, DL

SMALLEY, RE

机构：

[1] Department of Chemistry, William Marsh Rice University, Houston

来源：

JOURNAL OF CHEMICAL PHYSICS | 1979年 / 70卷 / 01期

关键词：

D O I：

10.1063/1.437221

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Oxalyl fluoride has been cooled to a rotational temperature of 0.17°K in a pulsed, supersonic jet. Individual rotational lines in the (0-0) band of the fluorescence excitation spectrum have been observed and assigned, and the rotational constants for both the 1Ag and 1Au states have been deduced. The pulsed nozzle used in these experiments can be operated with a far larger orifice diameter and at lower pressures than typically used in continuously operated nozzles, allowing greater cooling and higher jet densities while maintaining a low level of condensation. © 1979 American Institute of Physics.

引用

页码：192 / 198

页数：7

共 48 条

[1]

Allen Jr H. C., 1963, MOL VIB ROTORS

[2]

ANDRYUKHINA ED, 1961, PRIB TEKH EKSP, P174

[3]

Ashkenas H., 1966, RAREFIED GAS DYN, V2, P84

[4] ULTRAVIOLET ABSORPTION SPECTRA OF OXALYL HALIDES [J].

BALFOUR, WJ ;

KING, GW .

JOURNAL OF MOLECULAR SPECTROSCOPY, 1968, 25 (01) :130-&

[5]

BALFOUR WJ, 1967, THESIS MCMASTER U

[6]

BARONAVSKI AP, 1977, J CHEM PHYS, V67, P4286, DOI 10.1063/1.435367

[7]

BECK SM, 1979, J CHEM PHYS, V70, pR40

[8]

BIER K, 1966, 4 P S RAR GAS DYN, V2, P260

[9]

CAMPARGUE R, 1970, THESIS U PARIS

[10]

CAMPARGUE R, 1975, 5E S INT JETS MOL NI

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