CHEMISTRY OF ORGANOSILICON COMPOUNDS .125. NOVEL METHOD OF PREPARING ACYLSILANES FROM ALPHA-SILOXYALLYLSILANES BY TRANSITION-METAL CATALYZED ISOMERIZATION OF DOUBLE-BONDS

被引：18

作者：

HOSOMI, A

HASHIMOTO, H

SAKURAI, H

机构：

[1] Department of Chemistry, Faculty of Science, Tohoku University, Sendai

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 175卷 / 01期

关键词：

D O I：

10.1016/S0022-328X(00)82307-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Nine α-siloxyallylsilanes were prepared regiospecifically by silylation of metalated alkyl-substituted allyloxysilanes with chlorosilanes in good yieold. These compounds were converted readily to acylsilanes by transition metal-catalyzed isomerization of double bonds under neutral conditions. © 1979.

引用

页码：C1 / C4

页数：4

共 13 条

[1]

BIRCH AJ, 1976, TRANSITION METAL ORG, V1, P49

[2] NEW SYNTHESIS OF ACYLSILANES [J].