CHEMISTRY OF ORGANOSILICON COMPOUNDS .125. NOVEL METHOD OF PREPARING ACYLSILANES FROM ALPHA-SILOXYALLYLSILANES BY TRANSITION-METAL CATALYZED ISOMERIZATION OF DOUBLE-BONDS

被引:18
作者
HOSOMI, A
HASHIMOTO, H
SAKURAI, H
机构
[1] Department of Chemistry, Faculty of Science, Tohoku University, Sendai
关键词
D O I
10.1016/S0022-328X(00)82307-4
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Nine α-siloxyallylsilanes were prepared regiospecifically by silylation of metalated alkyl-substituted allyloxysilanes with chlorosilanes in good yieold. These compounds were converted readily to acylsilanes by transition metal-catalyzed isomerization of double bonds under neutral conditions. © 1979.
引用
收藏
页码:C1 / C4
页数:4
相关论文
共 13 条
[1]  
BIRCH AJ, 1976, TRANSITION METAL ORG, V1, P49
[2]   NEW SYNTHESIS OF ACYLSILANES [J].
BOURGEOIS, P ;
DUNOGUES, J ;
DUFFAUT, N ;
LAPOUYAD.P .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1974, 80 (02) :C25-C26
[3]   TRIPHENYLSILYL PHENYL KETONE [J].
BROOK, AG .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1957, 79 (16) :4373-4375
[4]   PHOTOLYSIS OF ACYL GROUP-IV METALLOIDS - FORMATION OF SILYL RADICALS [J].
BROOK, AG ;
DILLON, PJ ;
PEARCE, R .
CANADIAN JOURNAL OF CHEMISTRY, 1971, 49 (01) :133-&
[5]  
BROOK AG, 1968, ADVAN ORGANOMETAL CH, V7, P95, DOI DOI 10.1016/S0065-3055(08)60293-2
[6]  
BROOK AG, 1976, J AM CHEM SOC, V98, P3382
[7]  
HECK RF, 1974, ORGANOTRANSITION MET, P76
[8]   CHEMISTRY OF ORGANOSILICON COMPOUNDS .106. ALPHA-SILOXYALLYLSILANES AS HOMOENOLATE ANION EQUIVALENTS - NOVEL SYNTHESIS OF GAMMA-KETO ALDEHYDES [J].
HOSOMI, A ;
HASHIMOTO, H ;
SAKURAI, H .
JOURNAL OF ORGANIC CHEMISTRY, 1978, 43 (12) :2551-2552
[9]  
KEIM W, 1971, TRANSITION METALS HO, P81
[10]   REACTIONS OF LITHIUM ALKOXIDE OF 1,1-BIS(TRIMETHYLSILYL)ALKAN-1-OL WITH BENZOPHENONE - NOVEL WAY TO SILYL ENOL ETHER OF ACYLSILANE [J].
KUWAJIMA, I ;
ARAI, M ;
SATO, T .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (12) :4181-4182