SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF A TETRANUCLEAR ORGANOLANTHANIDE HYDRAZIDO COMPLEX

被引：28

作者：

WANG, KG ^{[1
]}

STEVENS, ED ^{[1
]}

NOLAN, SP ^{[1
]}

机构：

[1] UNIV NEW ORLEANS,DEPT CHEM,NEW ORLEANS,LA 70148

来源：

ORGANOMETALLICS | 1992年 / 11卷 / 03期

关键词：

D O I：

10.1021/om00039a003

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of Cp*2Sm (Cp* = eta(5)-C5Me5) with excess hydrazine leads to the formation of a yellow crystalline material in high yield. The product was structurally characterized by a single-crystal diffraction study which shows the molecule to consist of a distorted-tetrahedron arrangement of samarium atoms with bridging hydrazido anions on each edge of the tetrahedron.

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页码：1011 / 1013

页数：3

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