CHARACTERIZATION OF IMINOPROPADIENONE IONS AND NEUTRALS IN A TANDEM MASS-SPECTROMETER

被引：23

作者：

FLAMMANG, R ^{[1
]}

LAURENT, S ^{[1
]}

FLAMMANGBARBIEUX, M ^{[1
]}

WENTRUP, C ^{[1
]}

机构：

[1] UNIV QUEENSLAND,DEPT CHEM,BRISBANE,QLD 4072,AUSTRALIA

来源：

RAPID COMMUNICATIONS IN MASS SPECTROMETRY | 1992年 / 6卷 / 11期

关键词：

D O I：

10.1002/rcm.1290061108

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

Radical-cations of iminopropadienones (RN=C=C=C=O+.) have been generated by dissociative ionization of isoxazole precursors and structurally characterized by collisional activation mass spectrometry; the corresponding neutral cumulenes have also been produced in a tandem mass spectrometer by neutralization and/or flash-vacuum pyrolysis experiments.

引用

页码：667 / 670

页数：4

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