IONIC LIQUID MEDIATED PREPARATION AND X-RAY CRYSTAL-STRUCTURE OF [1-METHYLIMIDAZOLIUM]2[CIS-MOO2(SALICYLATO-O(1),O(2)2]

被引：8

作者：

BOUTILIER, K ^{[1
]}

MACGILLIVRAY, LR ^{[1
]}

SUBRAMANIAN, S ^{[1
]}

ZAWOROTKO, MJ ^{[1
]}

机构：

[1] ST MARYS UNIV,DEPT CHEM,HALIFAX B3H 3C3,NS,CANADA

来源：

JOURNAL OF CRYSTALLOGRAPHIC AND SPECTROSCOPIC RESEARCH | 1993年 / 23卷 / 10期

关键词：

D O I：

10.1007/BF01247239

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The complex salt, [1-MeimH]2[CiS-MoO2(sal)2], 1, (1-Meim = 1-methylimidazole, sal = o-C6H4(O-)(COO-)) has been prepared by reacting MO(CO)6 with molten 1-methyl imidazolium salicylate [1-MeimH][salH], and the structure of 1 has been determined by single crystal X-ray crystallography: triclinic, P1BAR, a = 9.220(2), b = 9.469(3), c = 15.368(4) angstrom, alpha = 105.04(4), beta = 99.48(3), gamma = 109.48(3)-degrees, Z = 2, D(calc) = 1.60 g/cm. 2809 reflections with I > 2.5sigma(I) gave a final values of R = 0.031 and R(w) = 0.041.

引用

页码：773 / 778

页数：6

共 32 条

[1]

[Anonymous], 1974, INT TABLES XRAY CRYS, VIV

[2]

ATOVMYAN LO, 1969, J CHEM SOC CHEM COMM, P649

[3] CRYSTAL MOLECULAR + ELECTRONIC STRUCTURES OF BINUCLEAR OXOMOLYBDENUM(V) XANTHATE COMPLEX [J].