HYDROGEN-BONDING IN THE COORDINATION OF N-DONOR AND S-DONOR HETEROCYCLES TO DIALKYLTIN DIHALIDES - SYNTHESIS AND STRUCTURE OF TRANS-DIBROMODICYCLOHEXYLBIS(PYRAZOLE-N2)TIN(IV), TRANS-DIBROMODICYCLOHEXYLBIS(IMIDAZOLE-N3)TIN(IV), AND DIBUTYLDICHLORO[1-METHYL-2(3H)-IMIDAZOLINETHIONE-S]TIN(IV)

被引：19

作者：

BANDOLI, G

DOLMELLA, A

PERUZZO, V

PLAZZOGNA, G

机构：

[1] UNIV PADUA,DIPARTIMENTO CHIM INORGAN MET ORGAN & ANALIT,VIA F MARZOLO 1,I-35131 PADUA,ITALY

[2] UNIV PADUA,DIPARTIMENTO SCI FARMACEUT,I-35131 PADUA,ITALY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 452卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(93)83171-Q

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Hexacoordinate octahedral crystalline complexes of dicyclohexyltin dibromide with pyrazole (1) and imidazole (2) have been prepared. The X-ray structures have been determined and the effect of the bulkiness of the alkyl groups bonded to the tin on aspects of the structures (such as intra-and inter-molecular hydrogen bonding, orientation of the ligand plane, and Sn-N bond length) is discussed. As an example of a pentacoordinate trigonal bipyramidal complex, the 1:1 adduct of dibutyltin dichloride with 1-methyl-imidazoline-2-thione (3) has been synthesized and its structure studied.

引用

页码：47 / 53

页数：7

共 22 条

[1] COMPLEXES OF DIMETHYLDIHALOTIN(IV) WITH IMIDAZOLE AND PYRAZOLE - THE CRYSTAL-STRUCTURE OF DIBROMOBIS(PYRAZOLE)DIMETHYLTIN(IV)
ALBERTE, B
GONZALEZ, AS
GARCIA, E
CASAS, JS
SORDO, J
CASTELLANO, EE
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1988, 338 (02) : 187 - 193
[2] CRYSTAL AND MOLECULAR STRUCTURE OF 2,3,4,4A,9,9A-HEXAHYDRO-2-METHYL-9-PHENYL-1H-INDENO[2,1-C]PYRIDINE HYDROBROMIDE, C19H22NBR
ALLEN, FH
ROGERS, D
TROUGHTO.PG
[J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL CRYSTALLOGRAPHY AND CRYSTAL CHEMISTRY, 1971, B 27 (JUL15): : 1325 - &
[3] [Anonymous], 1974, INT TABLES XRAY CRYS, VIV
[4] CRYSTAL AND MOLECULAR-STRUCTURES OF COMPLEXES OF VARIOUS METHYLTIN HALIDES WITH PYRIDINE
ASLANOV, LA
IONOV, VM
ATTIYA, VM
PERMIN, AB
PETROSYAN, VS
[J]. JOURNAL OF STRUCTURAL CHEMISTRY, 1978, 19 (01) : 166 - 169
[5] COMPLEXES OF BIS(CHLORODIMETHYLSTANNYL)METHANES AND BIS(DICHLOROMETHYLSTANNYL)METHANES WITH AROMATIC NITROGEN-HETEROCYCLES
AUSTIN, M
GEBREYES, K
KUIVILA, HG
SWAMI, K
ZUBIETA, JA
[J]. ORGANOMETALLICS, 1987, 6 (04) : 834 - 842
[6] POSSIBLE PRE-DISSOCIATION OF DIORGANOTIN DIHALIDE COMPLEXES - RELATIONSHIP BETWEEN ANTITUMOUR ACTIVITY AND STRUCTURE
CROWE, AJ
SMITH, PJ
CARDIN, CJ
PARGE, HE
SMITH, FE
[J]. CANCER LETTERS, 1984, 24 (01) : 45 - 48
[7] INVESTIGATIONS INTO THE ANTI-TUMOR ACTIVITY OF ORGANOTIN COMPOUNDS .1. DIORGANOTIN DIHALIDE AND DI-PSEUDOHALIDE COMPLEXES
CROWE, AJ
SMITH, PJ
ATASSI, G
[J]. CHEMICO-BIOLOGICAL INTERACTIONS, 1980, 32 (1-2) : 171 - 178
[8] CROWE AJ, 1980, CHEM IND-LONDON, P200
[9] GONZALEZ AS, 1988, J ORGANOMET CHEM, V353, P169
[10] SYNTHESIS AND MOLECULAR-STRUCTURE OF DICHLORODIVINYLBIS[(3H)-IMIDAZOLINE-2-THIONE]TIN(IV)
GRAZIANI, R
PERUZZO, V
PLAZZOGNA, G
CASELLATO, U
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 396 (01) : 19 - 23

← 1 2 3 →