COMPARATIVE KINETIC ANALYSES FOR EPOXY-RESINS CURED WITH IMIDAZOLE METAL-COMPLEXES

被引：31

作者：

BUIST, GJ ^{[1
]}

HAMERTON, I ^{[1
]}

HOWLIN, BJ ^{[1
]}

JONES, JR ^{[1
]}

LIU, SY ^{[1
]}

BARTON, JM ^{[1
]}

机构：

[1] DEF RES AGCY,CTR STRUCT MAT,FARNBOROUGH GU14 6TD,HANTS,ENGLAND

来源：

JOURNAL OF MATERIALS CHEMISTRY | 1994年 / 4卷 / 12期

关键词：

D O I：

10.1039/jm9940401793

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Proton nuclear magnetic resonance (H-1 NMR) spectroscopy experiments were carried out for a commercial epoxy resin system in [H-2(6)]DMSO solution and in bulk. Good agreement was obtained between the secondary rate constants found for the epoxide polyetherification reaction when monitored by Fourier-transform infrared (FTIR) or H-1 NMR spectroscopy in the bulk over the range of temperatures studied. This highlights the usefulness of the high temperature bulk NMR technique in kinetic studies of polymerization.

引用

页码：1793 / 1797

页数：5

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