NEW MATERIALS FOR SENSORS .1. TRIS(1,10-PHENANTHROLINE)IRON(II) COMPLEXES - INFLUENCE OF 4,7-DONOR SUBSTITUTION ON THE REDOX POTENTIAL

被引：19

作者：

LEVIS, M ^{[1
]}

LUNING, U ^{[1
]}

MULLER, M ^{[1
]}

SCHMITTEL, M ^{[1
]}

WOHRLE, C ^{[1
]}

机构：

[1] UNIV FREIBURG,CHEM LAB,D-79104 FREIBURG,GERMANY

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1994年 / 49卷 / 05期

关键词：

REDOX POTENTIAL; CYCLIC VOLTAMMETRY; ELECTRON TRANSFER; KINETICS WITH CHLORINE;

D O I：

10.1515/znb-1994-0519

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Several new 4,7-donor substituted 1,10-phenanthrolines were synthesized and the corresponding tris(1,10-phenanthroline)iron(II) complexes were studied by cyclic voltammetry. All iron(II) complexes showed fully reversible waves at scan rates between 50 and 500 mV/s. For some redox systems the kinetics in their reaction with chlorine was studied. Complexes 7k and 7l significantly extent the potential range of tris(1,10-phenanthroline)iron(II) complexes.

引用

页码：675 / 682

页数：8

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