CONJUGATIVE AND HOMO-CONJUGATIVE EFFECTS IN 2-HETEROBICYCLO[3.2.1]OCTA-3,6-DIENES

被引：8

作者：

BARRACLOUGH, P ^{[1
]}

BILGIC, S ^{[1
]}

PEDLEY, JB ^{[1
]}

ROGERS, AJ ^{[1
]}

YOUNG, DW ^{[1
]}

机构：

[1] UNIV SUSSEX,SCH MOLEC SCI,BRIGHTON BN1 9QJ,E SUSSEX,ENGLAND

来源：

TETRAHEDRON | 1979年 / 35卷 / 01期

关键词：

D O I：

10.1016/0040-4020(79)85014-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The 1H-NMR, 13C-NMR and photoelectron spectra of a variety of 2-heterobicyclo[3.2.1]octa-3,6-dienes 6 give evidence of conjugative and homoeonjugative effects in these compounds, but there is no suggestion from the data of any special contribution from the (4n+2)π neutral bishomoaromatic system. Reaction of the dienes6 with TCNE invariably yielded the product of [2+2] addition in cases where a fully characterisable product was obtained. © 1979.

引用

页码：99 / 103

页数：5

共 44 条

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