CHIRAL LITHIO FORMAMIDINES - ARE THEY CONFIGURATIONALLY STABLE

被引：43

作者：

MEYERS, AI

GUILES, J

WARMUS, JS

GONZALEZ, MA

机构：

[1] Department of Chemistry, Colorado State University, Fort Collins

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 40期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0040-4039(91)80069-I

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Metalation and alkylation of an optically active 1-methyl isoquinoline in the presence of an achiral formamidine leads to completely racemic material.

引用

页码：5505 / 5508

页数：4

共 20 条

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[2] GAWLEY, 1991, TETRAHEDRON LETT, V32, P1942
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[4] Lambert JB, 1971, TOP STEREOCHEM, V6, P19
[5] LETSINGER RL, 1950, J AM CHEM SOC, V72, P7842
[6] A NOVEL SYNTHESIS OF TETRAHYDROFURANS VIA A SYNTHETIC EQUIVALENT TO A CARBONYL YLIDE
LINDERMAN, RJ
GODFREY, A
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (18) : 6249 - 6251
[7] A TRIALKYLSTANNANE-MEDIATED APPROACH TO ACYLOIN PRODUCTS
MCGARVEY, GJ
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[J]. JOURNAL OF ORGANIC CHEMISTRY, 1985, 50 (23) : 4655 - 4657
[8] ASYMMETRIC-SYNTHESIS OF ISOQUINOLINE ALKALOIDS
MEYERS, AI
DICKMAN, DA
BOES, M
[J]. TETRAHEDRON, 1987, 43 (21) : 5095 - 5108
[9] MEYERS AI, 1988, ORG SYNTH, V67, P63
[10] MEYERS AI, TETRAHEDRON LETT

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