N-H VIS C-H ACTIVATION - A MAJOR LIGAND SIZE EFFECT

被引：55

作者：

SCHULZ, M ^{[1
]}

MILSTEIN, D ^{[1
]}

机构：

[1] WEIZMANN INST SCI,DEPT ORGAN CHEM,IL-76100 REHOVOT,ISRAEL

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 03期

关键词：

D O I：

10.1039/c39930000318

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The complexes trans-[Ir(PR3)2(C2H4)]Cl (3, R = Et; 4, R = Pr(i)) exhibit entirely different reactivity pathways with ammonia, whereas 3 undergoes N-H oxidative addition, 4 coordinates ammonia and undergoes C-H activation of the ethylene ligand at 25-degrees-C to yield an hydrido vinyl complex, and phosphine metallation at 80-degrees-C.

引用

页码：318 / 319

页数：2

共 33 条

[1] HOMOGENEOUS DEHYDROGENATION OF AMINES BY MU-(ETA1-ETA-5-CYCLOPENTADIENYL)-TRIS(ETA-CYCLOPENTADIENYL)DITITANIUM(TI-TI)
ARMOR, JN
[J]. INORGANIC CHEMISTRY, 1978, 17 (02) : 203 - 213
[2] BANASZAK MM, 1990, J AM CHEM SOC, V112, P7989
[3] PHOTOCHEMICAL ISOMERIZATION OF METAL ETHENE TO METAL VINYL HYDRIDE COMPLEXES - A MATRIX-ISOLATION AND SOLUTION NMR-STUDY
BELL, TW
HADDLETON, DM
MCCAMLEY, A
PARTRIDGE, MG
PERUTZ, RN
WILLNER, H
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (25) : 9212 - 9226
[4] REACTIONS OF ALKYL AND HYDRIDE DERIVATIVES OF PERMETHYLSCANDOCENE AND PERMETHYLZIRCONOCENE WITH NITRILES AND AMINES - CATALYTIC-HYDROGENATION OF TERT-BUTYL CYANIDE WITH PERMETHYLSCANDOCENE HYDRIDE
BERCAW, JE
DAVIES, DL
WOLCZANSKI, PT
[J]. ORGANOMETALLICS, 1986, 5 (03) : 443 - 450
[5] 1,1,2,2,2,2,3,3,3,3-DECACARBONYL-1-(ETA-CYCLOHEXA-1,3-DIENE)-TRIANGULO-TRIOSMIUM - NOVEL INTERMEDIATE IN SYNTHETIC OSMIUM CLUSTER CHEMISTRY
BRYAN, EG
JOHNSON, BFG
LEWIS, J
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1977, (14): : 1328 - 1330
[6] N-H ACTIVATION .1. OXIDATIVE ADDITION OF AMMONIA TO IRIDIUM(I) - ISOLATION, STRUCTURAL CHARACTERIZATION, AND REACTIVITY OF AMIDOIRIDIUM HYDRIDES
CASALNUOVO, AL
CALABRESE, JC
MILSTEIN, D
[J]. INORGANIC CHEMISTRY, 1987, 26 (07) : 971 - 973
[7] RATIONAL DESIGN IN HOMOGENEOUS CATALYSIS - IR(I)-CATALYZED ADDITION OF ANILINE TO NORBORNYLENE VIA N-H ACTIVATION
CASALNUOVO, AL
CALABRESE, JC
MILSTEIN, D
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (20) : 6738 - 6744
[8] TRANSITION METAL-CARBON BONDS .30. INTERNAL METALLATIONS OF PLATINUM(II) TERT BUTYLDI ORTHO TOLYLPHOSPHINE AND DI-T-BUTYL ORTH TOLYLPHOSPHINE COMPLEXES
CHENEY, AJ
SHAW, BL
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1972, (06): : 754 - &
[9] TRANSITION METAL-CARBON BONDS .31. INTERNAL METALLATIONS OF PALLADIUM(II)-TERT BUTYLDI-ORTHO TOLYLPHOSPHINE AND PALLADIUM(II)-DI-TERT BUTYL-ORTHO TOLYLPHOSPHINE COMPLEXES
CHENEY, AJ
SHAW, BL
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1972, (07): : 860 - &
[10] THE ORGANOMETALLIC CHEMISTRY OF ALKANES
CRABTREE, RH
[J]. CHEMICAL REVIEWS, 1985, 85 (04) : 245 - 269

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