POROUS PT/GAMMA-AL2O3 CATALYTIC MEMBRANE REACTORS PREPARED USING MESITYLENE SOLVATED PT ATOMS

被引：16

作者：

CAPANNELLI, G ^{[1
]}

BOTTINO, A ^{[1
]}

GAO, G ^{[1
]}

GROSSO, A ^{[1
]}

SERVIDA, A ^{[1
]}

VITULLI, G ^{[1
]}

MASTANTUONO, A ^{[1
]}

LAZZARONI, R ^{[1
]}

SALVADORI, P ^{[1
]}

机构：

[1] UNIV PISA,DIPARTIMENTO CHIM & CHIM IND,CNR,CTR MACROMOLEC STEREORDINATE & OTTICAMENTE ATT,I-58100 PISA,ITALY

来源：

CATALYSIS LETTERS | 1993年 / 20卷 / 3-4期

关键词：

MEMBRANE REACTORS; INORGANIC MEMBRANES; ORGANIC PRECURSORS; SOLVATED PLATINUM ATOMS; BENZENE HYDROGENATION;

D O I：

10.1007/BF00769301

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The opportunity of using mesitylene solvated Pt atoms for the deposition of Pt catalyst on inorganic membranes is shown. The catalytic activity of the membrane reactor has been tested using the hydrogenation of benzene as model reaction. The performance of the membrane reactor has been compared with that of a conventional packed bed using gamma-Al2O3 powder impregnated with Pt. The effect of the feeding configuration has been investigated, and the results show a membrane effect due to the different degrees of accessibility of pores of different size. For alumina powder we have obtained an activation energy of 12.9 kcal/ mol, which well agrees with the data reported in literature. The membrane reactor, instead, exhibited an activation energy ca. 60% lower. The preliminary porometry results have shown a slight effect of the platinum deposition process on membrane permeability.

引用

页码：287 / 297

页数：11

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