ORIENTATION EFFECTS IN THE DEUTERIUM NMR-SPECTROSCOPY OF PERFLUORINATED IONOMER MEMBRANES

被引:22
作者
RANKOTHGE, M
HARYADI
MORAN, G
HOOK, J
VANGORKOM, L
机构
[1] School of Chemistry, University of New South Wales, Kensington, NSW 2033
基金
澳大利亚研究理事会;
关键词
D O I
10.1016/0167-2738(94)90012-4
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The properties of water in Nafion(R) and Dow perfluorinated ionomer membranes in their protonated forms were investigated by proton and deuterium NMR spectroscopy. The H-2 quadrupolar splittings were shown to be dependent on the orientation of the membranes in the magnetic field as well as on their water content. The larger quadrupolar splittings found for Nafion are attributed to a greater degree of orientational order compared to the Dow samples. Hydrogen bonding, as evidenced by H-1 and H-2 chemical shifts, was very similar in the two types of membrane for a given relative humidity. The H-2 spin-lattice relaxation times (T1) were 93 and 109 ms for Nafion and Dow respectively at 300 K and 100% relative humidity, compared to 612 ms for D2O in 1:9 D2O:H2O. The temperature dependence of the T1 values was similar for the two membranes in the range 280-320 K and activation energies for molecular reorientation were estimated at 22 +/- 2 kJ mol-1, comparable to that for pure water in the same temperature range.
引用
收藏
页码:241 / 248
页数:8
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