PREPARATION OF CARBOSILANE DENDRIMERS WITH PERIPHERAL ACETYLENEDICOBALT HEXACARBONYL SUBSTITUENTS

被引：103

作者：

SEYFERTH, D ^{[1
]}

KUGITA, T ^{[1
]}

RHEINGOLD, AL ^{[1
]}

YAP, GPA ^{[1
]}

机构：

[1] UNIV DELAWARE,DEPT CHEM,NEWARK,DE 19716

来源：

ORGANOMETALLICS | 1995年 / 14卷 / 11期

关键词：

D O I：

10.1021/om00011a062

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The carbosilane dendrimers Si[CH(2)CH(2)SiMe(2)C=CH](4), 1, Si[CH(2)CH(2)SiMe(C=CH)(2)](4), 2, and Si[CH2CH2Si(CH(2)CH(2)SiMe(2)C=CH)(3)](4), 5, have been prepared. Reaction of Co-2(CO)(8) with all the C=CH groups in 1 and 5 gave the corresponding acetylenedicobalt hexacarbonyl complexes. The structure of Si[CH(2)CH(2)SiMe(2)-C2HCo2(CO)(6)](4) was determined in an X-ray diffraction study.

引用

页码：5362 / 5366

页数：5

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